A Radical-Polar Crossover Annulation To Access Terpenoid Motifs
收藏Figshare2019-07-22 更新2026-04-29 收录
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https://figshare.com/articles/dataset/A_Radical-Polar_Crossover_Annulation_To_Access_Terpenoid_Motifs/8985818
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A new catalytic radical-polar crossover annulation between two unsaturated carbonyl compounds is described. The annulation proceeds under exceptionally mild conditions and provides direct and expedient access to complex terpenoid motifs. Application of this chemistry allows for synthesis of forskolin, a densely functionalized terpenoid, in 14 steps from commercially available material.
创建时间：
2019-07-22
