Limits to scaling relations between adsorption energies?

Linear scaling relations have led to an understanding of trends in catalytic activity and selectivity of many reactions in heterogeneous and electro-catalysis. Yet, linear...线性标度关系（linear scaling relations）已使人们得以阐明多相催化（heterogeneous catalysis）与电催化（electro-catalysis）中诸多反应的催化活性与选择性变化趋势。然而，线性...