Sulfoxide-Directed Enantioselective Synthesis of Functionalized Tetrahydropyridines
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https://figshare.com/articles/dataset/Sulfoxide_Directed_Enantioselective_Synthesis_of_Functionalized_Tetrahydropyridines/2370253
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The highly selective base-promoted cyclization of enantiopure sulfinyl dienamines provides stereodefined sulfinyl 1,2,3,6-tetrahydropyridines (dr up to 99:1). Subsequent sigmatropic rearrangement affords tetrahydropyridin-3-ols in good yields and selectivities.
创建时间：
2016-02-18
