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Stereocontrolled Synthesis of <i>trans</i>-Cyclopropyl Sulfones from Terminal Epoxides

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NIAID Data Ecosystem2026-03-06 收录
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Treatment of a range of (enantiopure) epoxides with the sodium salt of diethyl (phenylsulfonyl)methylphosphonate in DME at 140 °C for 4 h gives a variety of (enantiopure) trans-cyclopropyl sulfones with high diastereoselectivity.

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2010-07-02
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