Synthesis of Bowl-Shaped Polycyclic Aromatic Hydrocarbons via Palladium-Catalyzed Intramolecular Arylation Reactions
收藏NIAID Data Ecosystem2026-03-06 收录
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Treatment of the benzannulated enediyne 11 with potassium tert-butoxide in refluxing toluene for 12 h produced 15 via a cascade sequence of cyclization reactions. Two subsequent palladium-catalyzed intramolecular arylation reactions then afforded the bowl-shaped polycyclic aromatic hydrocarbon 16. The X-ray structures of 16 and two closely related molecules show the presence of significant curvatures.
创建时间：
2016-05-05
