Synthesis and Optical Properties of Stable Gallafluorene Derivatives: Investigation of Their Emission via Triplet States
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We designed and synthesized air- and moisture-stable gallafluorenes in which two benzene rings were bridged by the four-coordinate gallium atoms. The series of gallafluorenes were prepared by introducing electron-donating and -withdrawing groups through Suzuki–Miyaura coupling reactions. The gallafluorenes showed unique emissions via their triplet states in the presence of B(C6F5)3. These emissions were obtained via the triplet exciplex of gallafluorene and B(C6F5)3.
创建时间：
2016-02-19
