Concise Synthesis of Enantiopure (<i>S</i>)-(<i>+</i>)-2,2′-Bis(<i>tert</i>-butyldimethylsilyl)-1,1′-diphosphaferrocene: Anion-Dependence of Its Coordination to Palladium(II) Centers
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A convenient synthesis of enantiopure (S)-(+)-2,2′-bis(tert-butyldimethylsilyl)-3,3′,4,4′-tetramethyl-1,1′-diphosphaferrocene is described. The compound shows unusual coordination properties with respect to Otsuka’s Pd(II) dimer di-(S)-chloro-[1-[1-(dimethylamino)ethyl]-2-naphthyl-C,N]palladium(II)].
创建时间：
2009-01-12
