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A 3-D Noninterpenetrating Diamondoid Network of a Decanuclear Copper(I) Complex

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https://figshare.com/articles/dataset/A_3_D_Noninterpenetrating_Diamondoid_Network_of_a_Decanuclear_Copper_I_Complex/3286216
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The solvothermal reaction of CuCl2·2H2O with pyridine-4-thiol and ethanol yielded a novel photoluminescent 3-D polymeric complex with an interesting decorated diamondoid network that is constructed of decanuclear copper(I) cluster units and μ4-Cl ligands. The in situ generation of CuSO4·5H2O implies the spontaneous occurrence of desulfurization and redox reactions in the present system.
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2016-05-06
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