Stereospecific Substitution of Allylic Alcohols To Give Optically Active Primary Allylic Amines: Unique Reactivity of a (P,alkene)Ir Complex Modulated by Iodide
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A stereospecific allylic amination of unactivated secondary (2°)-allylic alcohols is reported. The primary (1°)-allylic amine can be isolated directly or protected in situ. Spectroscopic studies have shed light on the structure of the catalytically active Ir•(P,olefin)2I complex.
创建时间：
2010-09-01
