[LiCH<sub>2</sub>SPh(pmdta)]: A Carbenoid
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资源简介：
The monomeric complex [LiCH2SPh(pmdta)] (3; pmdta = N,N,N‘,N‘ ‘,N‘ ‘-pentamethyldiethylenetriamine), prepared by metalation of PhSCH3 with n-BuLi/pmdta, undergoes in toluene (room temperature, in daylight) extrusion of the methylene group with formation of [LiSPh(pmdta)] and CH4. In refluxing toluene this reaction is thermally induced and the dimerizing α-elimination of 3 proceeds with formation of [LiSPh(pmdta)] and H2CCH2.
创建时间：
2016-08-26
