Silver-Promoted Oxidative Cyclization of 1,6-Enynes: Highly Regioselective Synthesis of Phosphorated Fluorene Derivatives
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A silver-promoted oxidative cyclization of 1,6-enynes with disubstituted phosphine oxides is developed for the synthesis of fluorene derivatives. The reaction proceeds with high regioselectivity by constructing one C–P bond and two C–C bonds in one step. Moreover, reduction of the pentavalent phosphine enlarges the application scope of the product.
创建时间：
2016-02-16
