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Creating Quaternary Centers with High Exo Stereoselectivity Using Activated α-Alkynyl Dienophiles

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NIAID Data Ecosystem2026-03-06 收录
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Ethynyl substituents were used to direct a highly exoselective creation of quaternary carbon centers in Diels−Alder cycloaddition reactions involving activated α-alkynyl dienophiles. The origins of electronic activation and the high stereoselectivities of these reactions were investigated by the B3LYP density functional method.

创建时间:
2016-02-28
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