Catalytic Suzuki Coupling Reactions by Amido Phosphine Complexes of Palladium
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https://figshare.com/articles/dataset/Catalytic_Suzuki_Coupling_Reactions_by_Amido_Phosphine_Complexes_of_Palladium/3302980
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资源简介：
Treatment of PdCl2(PhCN)2 with [NP]Li(THF)2 ([NP]- = N-(2-(diphenylphosphino)phenyl)-2,6-diisopropylanilide) in THF affords dimeric {[NP]PdCl}2, which reacts with tricyclohexylphosphine to produce [NP]PdCl(PCy3). The two phosphorus donors in [NP]PdCl(PCy3) are
mutually cis, as indicated by the solution NMR and X-ray crystallographic studies. Both
{[NP]PdCl}2 and [NP]PdCl(PCy3) are highly active catalyst precursors for Suzuki coupling
reactions of a wide array of aryl halides, including those featuring electronically deactivated
and sterically hindered characteristics.
创建时间：
2016-05-06
