I2‑Promoted Selective Oxidative Cross-Coupling/Annulation of 2‑Naphthols with Methyl Ketones: A Strategy To Build Naphtho[2,1‑b]furan-1(2H)‑ones with a Quaternary Center
收藏Figshare2016-02-17 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/I_sub_2_sub_Promoted_Selective_Oxidative_Cross_Coupling_Annulation_of_2_Naphthols_with_Methyl_Ketones_A_Strategy_To_Build_Naphtho_2_1_i_b_i_furan_1_2_i_H_i_ones_with_a_Quaternary_Center/2313127
下载链接
链接失效反馈官方服务：
资源简介：
A highly efficient and selective molecular iodine-promoted oxidative cross-coupling/annulation between 2-naphthols and methyl ketones has been realized. The reaction successfully constructed a new quaternary carbon center within 3(2H)-furanones. Our synthetic strategy provided an in situ iodination-based oxidative coupling pathway. Based on the experimental results, a self-sequenced iodination/Kornblum oxidation/Friedel–Crafts/oxidation/cyclization mechanism was proposed.
创建时间：
2016-02-17
