N‑Phosphorylated Azolylidenes: Novel Ligands for Dinuclear Complexes of Coinage Metals
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https://figshare.com/articles/dataset/N_Phosphorylated_Azolylidenes_Novel_Ligands_for_Dinuclear_Complexes_of_Coinage_Metals/2449285
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资源简介:
Dinuclear silver(I) complexes with bridging N-phosphorylated
azolylidene
ligands have been synthesized. Subsequent transfer of the ligands
to other group 11 metal centers (Cu, Au) has been accomplished, highlighting
the usefulness of the silver complexes as an easy to handle, air-
and moisture-stable source of these ligands. Preliminary results indicate
that dinuclear copper(I) complexes with N-phosphorylated imidazolylidene
ligands display notable catalytic efficiency in nitrene transfer reactions.
创建时间:
2013-01-28



