[Ir(cod)<sub>2</sub>]BARF-Catalyzed C–H Bond Alkenylation and Alkylation of Ferrocenes
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[Ir(cod)2]BARF [BARF = tetrakis(3,5-trifluoromethylphenyl)borate] catalyzed the directed alkenylation and alkylation of ferrocenes to form a variety of tri- and disubstituted ferrocenes. Mechanistic investigation revealed several putative intermediates along with the importance of COD (1,5-cyclooctadiene), as a diene ligand, and a possible catalyst deactivation pathway. On the basis of the mechanistic investigation, catalytic activity was further improved.
创建时间：
2012-06-11
