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K<sub>3</sub>Ln(AsS<sub>4</sub>)<sub>2</sub> (Ln = Nd, Sm, Gd): the First Rare Earth Thioarsenate Compounds with Infinite Straight Chains

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The structures of the novel compounds K3Ln(AsS4)2 (Ln = Nd, Sm, Gd) contain infinite straight (AsS4)2]3- anionic chains which are composed of interconnected LnS8 polyhedra and AsS4 tetrahedra. The compounds were synthesized via reactions of Ln metals with in-situ-formed potassium polythioarsenate fluxes.

创建时间:
2016-02-29
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