Asymmetric Homoenolate Additions to Acyl Phosphonates through Rational Design of a Tailored N‑Heterocyclic Carbene Catalyst
收藏Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Asymmetric_Homoenolate_Additions_to_Acyl_Phosphonates_through_Rational_Design_of_a_Tailored_i_N_i_Heterocyclic_Carbene_Catalyst/2334508
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资源简介：
A highly selective NHC-catalyzed synthesis of γ-butyrolactones from the fusion of enals and α-ketophosphonates has been developed. Computational modeling of competing transition states guided a rational design strategy to achieve enhanced levels of enantioselectivity with a new tailored C1-symmetric biaryl-saturated imidazolium-derived NHC catalyst.
创建时间：
2016-02-18
