Synthesis, crystal structure and catalytic property of a cadmium(II) coordination polymer derived from a zwitterionic carboxylate ligand
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A new Cadmium(II) zwitterionic coordination polymer, {[Cd(cbdcp)(H<sub>2</sub>O)<sub>4</sub>]·H<sub>2</sub>O}<sub>n</sub>, (1) was synthesized based on the 1-(3,5-dicarboxybenzyl)-4,4′-bipyridinium bromide (H<sub>3</sub>cbdcpBr) organic linker. In 1, Cd(II) cations are connected by cbdcp<sup>2−</sup> anions to form a one-dimensional chain structure, which are further connected to generate a hydrogen bonded-extended three-dimensional supramolecular network. Furthermore, thermal stability and catalyitic activity of 1 have also been investigated.
创建时间:
2019-02-01



