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Highly Stereocontrolled Synthesis of Natural Barbacenic Acid, Novel Bisnorditerpene from <i>Barbacenia </i><i>f</i><i>lava</i>

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NIAID Data Ecosystem2026-03-06 收录
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Barbacenic acid, a bisnorditerpene with five contiguous asymmetric centers (four fully substituted), has been prepared for the first time through a highly stereocontrolled route in 5.2% overall yield from a known octalone. The synthesis serves to define the absolute configuration of the natural product.

创建时间:
2016-08-19
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