Catalytic Cycloalumination for the Synthesis of Norbornane-Annulated Phospholanes
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https://figshare.com/articles/dataset/Catalytic_Cycloalumination_for_the_Synthesis_of_Norbornane_Annulated_Phospholanes/2217844
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资源简介：
An
effective one-pot method for the synthesis of polycyclic phospholanes
by in situ reaction of dichlorophosphines (RPCl2, where R = Ph, t-Bu, Me) with norbornane-annulated
aluminacyclopentanes was obtained by catalytic cycloalumination of
norbornenes. Oxidation of phospholanes gave the corresponding polycyclic
phospholane 3-oxides (3-sulfides). The molybdenum complex L2Mo(CO)4 (L = 3-phenyl-3-phosphatricyclo[5.2.1.02,6]decane) was prepared for the first time by the reaction
of 3-phenyl-3-phosphatricyclo[5.2.1.02,6]decane with
molybdenum hexacarbonyl. The structures of the obtained compounds
were confirmed by X-ray diffraction and multinuclear 1H, 13C, and 31P NMR spectroscopy.
创建时间：
2016-02-16
