five

Bifunctional [c2]Daisy-Chains and Their Incorporation into Mechanically Interlocked Polymers

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Bifunctional_c2_Daisy_Chains_and_Their_Incorporation_into_Mechanically_Interlocked_Polymers/2994364
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A strategy for the formation of mechanically interlocked polymers is presented. Ring-closing olefin metathesis has been shown to provide a very high yielding route to [c2]daisy-chains suitably functionalized to allow their one-step conversion to bisolefins which can be used as monomers in ADMET polymerizations to afford mechanically interlocked polymers. Metathesis, in two different guises is making a hitherto unreachable goal in synthesis a reality.
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2007-07-25
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