Reversible Concerted Metalation–Deprotonation C–H Bond Activation by [Cp*RhCl<sub>2</sub>]<sub>2</sub>
收藏NIAID Data Ecosystem2026-03-11 收录
数据链接：
官方服务：
资源简介：
The reversibility of the concerted metalation–deprotonation exchange of eight para-substituted phenylpyridines is examined with the parent Cp*RhCl(κ-C,N-NC5H4–C6H4). Equilibrium constants are determined, and the free energies are used to extract the most important parameters that control the thermodynamics. Keq values are found to correlate best with heterolytic C–H bond strengths but in a way that is not obvious considering the electrophilic nature of these activations.
创建时间：
2019-09-10
