Cooling of Melts: Kinetic Stabilization and Polymorphic Transitions in the KInSnSe<sub>4</sub> System
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Through a flame-melting/rapid-cooling process, metastable forms of solid state compounds can be discovered. We describe here an example where both slow and rapid crystallizations of a stoichiometric “KInSnSe4” melt give rise to kinetic forms of KInSnSe4. These forms (α- and β-) convert to the thermodynamically stable γ-form upon heating below the melting point.
创建时间:
2016-05-07



