Iron-Catalyzed C–H Borylation of Arenes
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https://figshare.com/articles/dataset/Iron_Catalyzed_C_H_Borylation_of_Arenes/2182054
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资源简介：
Well-defined iron bis(diphosphine)
complexes are active catalysts
for the dehydrogenative C–H borylation of aromatic and heteroaromatic
derivatives with pinacolborane. The corresponding borylated
compounds were isolated in moderate to good yields (25–73%)
with a 5 mol% catalyst loading under UV irradiation (350 nm) at room
temperature. Stoichiometric reactivity studies and isolation of an
original trans-hydrido(boryl)iron complex,
Fe(H)(Bpin)(dmpe)2, allowed us to propose a
mechanism showing the role of some key catalytic species.
创建时间：
2016-02-13
