Catalytic Enantioselective Total Synthesis of Hypocrolide A
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https://figshare.com/articles/dataset/Catalytic_Enantioselective_Total_Synthesis_of_Hypocrolide_A/3823323
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资源简介：
The first and catalytic enantioselective total synthesis of hypocrolide A (>99% ee) in 12 steps, as well as other botryanes, is described. The absolute configurations of these compounds have been unambiguously confirmed or reassigned accordingly. The key reactions in this study include an unusual rhodium-catalyzed intramolecular [4 + 2] cycloaddition and a biomimetic oxidative [3 + 2] cycloaddition based on our revised biogenetic pathway.
创建时间：
2016-10-03
