Toluene and α‑Olefins as Radical Scavengers: Direct NMR Evidence for Homolytic Chain Transfer Mechanism Leading to Benzyl and “Dormant” Titanium Allyl Complexes
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下载链接：
https://figshare.com/articles/dataset/Toluene_and_Olefins_as_Radical_Scavengers_Direct_NMR_Evidence_for_Homolytic_Chain_Transfer_Mechanism_Leading_to_Benzyl_and_Dormant_Titanium_Allyl_Complexes/7327376
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资源简介：
Resting/dormant benzyl-
and allyl-type Ti(IV) complexes formed
under α-olefin polymerization conditions have been detected
and characterized by NMR. Experimental and computational evidence
supports a formation mechanism via reversible Ti–C bond homolysis
rather than “classical” σ-bond metathesis.
创建时间：
2018-11-30
