Toluene and α‑Olefins as Radical Scavengers: Direct NMR Evidence for Homolytic Chain Transfer Mechanism Leading to Benzyl and “Dormant” Titanium Allyl Complexes
收藏NIAID Data Ecosystem2026-03-10 收录
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资源简介：
Resting/dormant benzyl- and allyl-type Ti(IV) complexes formed under α-olefin polymerization conditions have been detected and characterized by NMR. Experimental and computational evidence supports a formation mechanism via reversible Ti–C bond homolysis rather than “classical” σ-bond metathesis.
创建时间：
2018-11-30
