Four-Electron Reduction of a New Ruthenium Dicarbonyl Complex Having Two NAD Model Ligands through Decarboxylation in Water
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https://figshare.com/articles/dataset/Four-Electron_Reduction_of_a_New_Ruthenium_Dicarbonyl_Complex_Having_Two_NAD_Model_Ligands_through_Decarboxylation_in_Water/4203084
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资源简介：
Three Ru–CO
complexes, [Ru(pbn)2(CO)2]2+, [Ru(pbn)2(CO)(COOH)]+, [Ru(pbn)2(CO)(COO)]0 [pbn = 2-(pyridin-2-yl)benzo[b]-1,5-naphthyridine],
exist as equilibrium mixtures in aqueous solutions. Thermal decarboxylation
of [Ru(pbn)2(CO)(COOH)]+ and/or [Ru(pbn)2(CO)(COO)]0 induces a two-electron reduction of
pbn to form [Ru(pbn)(pbnHH)(CO)(OH2)]2+ [pbnHH
= 2-(pyridin-2-yl)-5,10-dihydrobenzo[b]-1,5-naphthyridine]
in H2O.
创建时间：
2016-11-15
