Catalyst-Controlled Chemodivergent Reactivity of Vinyl Cyclopropanes: A Selective Approach toward Indoles and Aniline Derivatives
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https://figshare.com/articles/dataset/Catalyst-Controlled_Chemodivergent_Reactivity_of_Vinyl_Cyclopropanes_A_Selective_Approach_toward_Indoles_and_Aniline_Derivatives/21676560
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资源简介：
Herein, we disclose a catalyst-controlled
chemodivergent
approach
to access C2-substituted indoles and diverse aniline derivatives with
good chemo- and stereoselectivity by employing vinylcyclopropanes
(VCPs) as coupling partners via a tandem C–H/C–C activation/annulation
strategy. The key feature of this work is the divergent reactivity
profile showcased by VCPs, going beyond allylation under a high-valent
Rh-/MPAA catalyst system.
创建时间：
2022-12-05
