Ruthenium-Catalyzed C–H Alkynylation of Aromatic Amides with Hypervalent Iodine–Alkyne Reagents
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https://figshare.com/articles/dataset/Ruthenium-Catalyzed_C_H_Alkynylation_of_Aromatic_Amides_with_Hypervalent_Iodine_Alkyne_Reagents/3467777
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资源简介：
An
efficient C–H activation method for the ortho alkynylation of aromatic N-methoxyamides with hypervalent
iodine–alkyne reagent using a ruthenium catalyst is described.
The reaction proceeds under mild reaction conditions with broad substrate
scope. A possible catalytic cycle involving a ruthenium carboxylate
assisted C–H bond cleavage is proposed from the preliminary
mechanistic evidence.
创建时间：
2016-07-11
