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Total Synthesis of (−)-Carinatine A and (+)-Lycopladine A

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Figshare2016-08-29 更新2026-04-29 收录
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An efficient synthesis of two Lycopodium alkaloids, (−)-carinatine A and (+)-lycopladine A, is achieved in eight steps. The synthesis features an intramolecular aldol reaction for assembling the 6,5-fused ring system, a subsequent Tsuji-Trost allylation for generating a quarternary carbon center, and a 6π-electrocyclization to form the pyridine ring.

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2016-08-29
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