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Inverted Sapphyrin: A New Family of Doubly N-Confused Expanded Porphyrins

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Inverted_Sapphyrin_A_New_Family_of_Doubly_N_Confused_Expanded_Porphyrins/3055753
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The synthesis of an inverted, methoxylated sapphyrin derivative is described. This system, wherein inversion of pyrrolic nitrogen atoms is configurationally enforced via the use of a 3,3‘-bipyrrolic precursor, displays what is best described as “weak aromaticity” as judged from its spectroscopic features and supporting theoretical calculations.
创建时间:
2016-02-29
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