Novel Cluster Coordination Polymers Based on Tetranuclear Nest-Shaped [WOS<sub>3</sub>Cu<sub>3</sub>] Heterothiometallitic Secondary Building Units and 4,4‘-Bipyridine Ligand
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
Two novel cluster coordination polymers, {[W4O4S12Cu12Cl2(4,4‘-bipy)12]2Cl.4H2O}n (1) and {[(n-Bu)4N]2[W2O2S6Cu6Br4(4,4‘-bipy)3]}n (2) (4,4‘-bipy = 4,4‘-bipyridine), based on tetranuclear nest-shaped heterothiometallatillic secondary building units [WOS3Cu3] have been synthesized and characterized by X-ray diffraction. Compound 1 shows a 3D 3-fold interpenetrated cationic diamondoid structure, whereas compound 2 shows a 1D anionic zigzag pattern. Both of them exhibit excellent third-order nonlinear optical (NLO) properties.
创建时间：
2016-10-12
