Efficient and Mild Carbon Dioxide Hydrogenation to Formate Catalyzed by Fe(II) Hydrido Carbonyl Complexes Bearing 2,6-(Diaminopyridyl)diphosphine Pincer Ligands
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https://figshare.com/articles/dataset/Efficient_and_Mild_Carbon_Dioxide_Hydrogenation_to_Formate_Catalyzed_by_Fe_II_Hydrido_Carbonyl_Complexes_Bearing_2_6_Diaminopyridyl_diphosphine_Pincer_Ligands/3159568
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资源简介：
Fe(II)
hydrido carbonyl complexes supported by PNP pincer ligands
based on the 2,6-diaminopyridine scaffold were found to promote the
catalytic hydrogenation of CO2 and NaHCO3 to
formate in protic solvents in the presence of bases, reaching quantitative
yields and high TONs under mild reaction conditions, with pressures
as low as 8.5 bar and temperatures as low as 25 °C. NMR and DFT
studies highlighted the role of dihydrido and hydrido formate complexes
in catalysis.
创建时间：
2016-05-02
