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One-Pot Formation and Characterization of Macrocyclic Aromatic Tetrasulfonates

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NIAID Data Ecosystem2026-03-06 收录
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Aromatic tetrasulfonate macrocycles were prepared in one pot by treating arenedisulfonyl chlorides with dihydroxyarenes. X-ray structures revealed that these cyclic molecules have noncollapsible cavities and well-defined conformations resembling the cone and partial cone conformations of calix[4]arenes. Incorporating aromatic residues of different sizes leads to macrocycles with different cavity sizes.

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2009-02-19
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