Aziridine Opening via a Phenonium Ion Enables Synthesis of Complex Phenethylamine Derivatives
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https://figshare.com/articles/dataset/Aziridine_Opening_via_a_Phenonium_Ion_Enables_Synthesis_of_Complex_Phenethylamine_Derivatives/17705571
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资源简介：
We
report that the treatment of unsymmetrical 2,3-disubstituted
aziridines with TiCl4 yields β-phenethylamine products
via the intermediacy of a phenonium ion. Derivatization of the products
obtained via this method is demonstrated. Computational analysis of
the reaction pathway provides insight into the reaction mechanism,
including the selectivity of the phenonium opening.
创建时间：
2021-12-30
