Annulative Methods Enable a Total Synthesis of the Complex Meroterpene Berkeleyone A
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https://figshare.com/articles/dataset/Annulative_Methods_Enable_a_Total_Synthesis_of_the_Complex_Meroterpene_Berkeleyone_A/4214784
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资源简介：
Synthetic
pathways to complex meroterpenes derived from 3,5-dimethylorsellinic
acid (DMOA) and farnesyl pyrophosphate have not been reported despite
heavy biosynthetic and medicinal interest. Herein we report the first
total synthesis of berkeleyone A, a potential gateway compound to
a plethora of fungal-derived meroterpenes, in 13 steps. In addition,
we have further developed a novel annulation reaction for the synthesis
of hydroxylated 1,3-cyclohexadiones in a single step.
创建时间：
2016-11-10
