(<i>R</i>/<i>S</i>)<sub>A2</sub>- or (<i>R</i>,<i>S</i>/<i>S</i>,<i>R</i>)<sub>p,p</sub><sub>‘</sub>-[Pd(κ<sup>2</sup>-<i>P</i>,<i>P</i>-{P(OC<sub>6</sub>H<sub>3</sub>Bu<sup>t</sup><sub>2</sub>-2,4)<sub>2</sub>N(Me)C(O)N(Me)PPh<sub>2</sub>}Cl<sub>2</sub>]: Chirality Created by Ring Tilting
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The reaction of the unsymmetric bisphosphanyl urea ligand P(OC6H3But2-2,4)2N(Me)C(O)N(Me)PPh2 with [Pd(cod)Cl2] (cod = 1,5-cyclooctadiene) results in the chiral palladacycle (R,S)A2-[Pd(κ2-P,P-{P(OC6H3But2-2,4)2N(Me)C(O)N(Me)PPh2}Cl2]. The chirality of the title compound is caused by the tilting of the central, six-membered PdP2N2C ring along one of the two P−N vectors and comprises two chiral planes and one chiral axis.
创建时间：
2016-05-06
