Direct Synthesis of Chiral Tertiary Diphosphines via Pd(II)-Catalyzed Asymmetric Hydrophosphination of Dienones
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A highly diastereo- and enantioselective Pd(II)-catalyzed hydrophosphination of dienones with Ph2PH involving formation of double C*–P bonds has been developed, providing a series of chiral tertiary diphosphines (chiral PCP pincer ligands) in high yields. A catalytic cycle for the reaction was proposed.
创建时间：
2016-02-22
