Redox Behavior of an Organometallic Palladium(II)/Palladium(IV) System. A New Method for the Synthesis of Cationic Palladium(IV) Complexes
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https://figshare.com/articles/dataset/Redox_Behavior_of_an_Organometallic_Palladium_II_Palladium_IV_System_A_New_Method_for_the_Synthesis_of_Cationic_Palladium_IV_Complexes/3277063
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资源简介:
A new method for the synthesis of cationic Pd(IV) complexes, based on the chemical
oxidation of an anionic Pd(II) metallacycle in the presence of an additional ligand, is
presented. Electrochemical analysis of these compounds reveals that the stability of the +4
oxidation state is sensitive to the electron-donor capability of the added co-ligand and to the
steric features of the Tp‘ ligand.
创建时间:
2016-05-05



