A New Oxomolybdate Component Extracted from the “Virtual Dynamic Library” Yielding the Macrocyclic Anion [(Mo<sup>VI</sup><sub>8</sub>O<sub>28</sub>)<sub>4</sub>(Mo<sup>V</sup><sub>2</sub>O<sub>2</sub>S<sub>2</sub>)<sub>4</sub>]<sup>24−</sup>
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A rare isomer of the {Mo8O28}8− anion has been trapped from an acidified aqueous solution of molybdate by using the {Mo2O2S2}2+ oxothio cation as the linker and isolated as a part of a unique macrocyclic anion, which consists of four isopolyoxomolybdate fragments {Mo8O28} bridged by four {Mo2O2S2} units.
创建时间:
2010-11-01



