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Transmetalation of Phenylplatinum(II) Complex. Isolation and Characterization of a Dinuclear Intermediate in Intermolecular Phenyl Ligand Transfer

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https://figshare.com/articles/dataset/Transmetalation_of_Phenylplatinum_II_Complex_Isolation_and_Characterization_of_a_Dinuclear_Intermediate_in_Intermolecular_Phenyl_Ligand_Transfer/3321658
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资源简介:
PtI(Ph)(cod) reacts with TBA+OH- (TBA = tetra-n-butylammonium) to form PtPh2(cod) via intermolecular phenyl ligand transfer. An intermediate dinuclear Pt complex with the bridging OH ligand, [{Pt(Ph)(cod)}2(μ-OH)]+, was isolated and fully characterized.
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2016-05-06
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