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Transmetalation of Phenylplatinum(II) Complex. Isolation and Characterization of a Dinuclear Intermediate in Intermolecular Phenyl Ligand Transfer

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NIAID Data Ecosystem2026-03-06 收录
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PtI(Ph)(cod) reacts with TBA+OH- (TBA = tetra-n-butylammonium) to form PtPh2(cod) via intermolecular phenyl ligand transfer. An intermediate dinuclear Pt complex with the bridging OH ligand, [{Pt(Ph)(cod)}2(μ-OH)]+, was isolated and fully characterized.

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2016-05-06
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