Mn<sub>8</sub>@Na<sub>8</sub> Cube-in-Cube SBBs-Based Heterometallic Coordination Network with Unprecedented (3<sup>9</sup>.4<sup>6</sup>)<sub>8</sub> Topological Mn<sub>8</sub>(μ<sub>4</sub>‑OMe)<sub>6</sub> Cubes
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A novel body-centered cubic antiferromagnetic heterometal-coordination network Na4Mn8(μ4-OMe)6(μ4-MeCO2)12 ·2MeCO2 based on Mn8@Na8 cube-in-cube supramolecular building blocks has been synthesized, in which the unprecedented cubic (39.46)8 topological Mn8(μ4-OMe)6 cube with capped oxygen of five coordination is first revealed. Interestingly, the cube-in-cube Mn8@Na8 in combination with coordinated oxygen atoms makes up the unique nested Mn8O6@O24@Na8 triple-shell structure, in which the inner Mn8 cube is penetrated by the O6 octahedron but is enclosed by a larger O24 truncated cube that is further surrounded by a still larger Na8 cube.
创建时间：
2016-02-19
