Gold Phenolate Complexes: Synthesis, Structure, and Reactivity
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https://figshare.com/articles/dataset/Gold_Phenolate_Complexes_Synthesis_Structure_and_Reactivity/2415874
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资源简介：
Seven
different NHC gold(I) phenolate complexes were synthesized. Structural
data, including X-ray crystal structure analyses, could be obtained
for each of them. An investigation by computational chemistry, including
NBO analysis, indicates three-center–four-electron hyperbonds
among the carbene carbon, the gold atom, and the oxygen atom of the
phenolate with an approximate 60:40 distribution of the bonding interaction
in favor of the carbene–gold bond. The new class of complexes
shows only moderate catalytic activity.
创建时间：
2016-02-19
