Synthesis of Fully Substituted Polyhydroxylated Pyrrolizidines via Cope–House Cyclization
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https://figshare.com/articles/dataset/Synthesis_of_Fully_Substituted_Polyhydroxylated_Pyrrolizidines_via_Cope_House_Cyclization/2622494
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Total synthesis of the proposed structure of (−)-hyacinthacine C5 and its epimers at C6 and C7 is described. A key step of the synthesis was the construction of the bicyclic pyrrolizidine system by means of a nucleophilic addition of a dithiane to a cyclic nitrone followed by a Cope–House cyclization.
创建时间：
2016-02-23
