From Pincers to Steps: Synthesis, Structure, Characterization, and Transformation of a New Helical Calcium−Organic Framework, Ca[NC<sub>5</sub>H<sub>3</sub>(CO<sub>2</sub>)<sub>2</sub>](H<sub>2</sub>O)<sub>1.5</sub>
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Unprecedented 1-D helical calcium−organic framework material, Ca[NC5H3(CO2)2](H2O)1.5, has been synthesized for the first time under hydrothermal reaction conditions using Ca(OH)2, 2,6-NC5H3(CO2H)2, (CH3)2NCOH, HNO3, and H2O as reagents. A complete characterization including the transformation of the helical chain with pincers to another helix with steps by the reaction with water is reported.
创建时间:
2011-04-06



