Towards the Rational Synthesis of Norfullerenes. Controlled Deletion of One Carbon Atom from C<sub>60</sub> and Preparation of 2,5,9-Trioxo-1-nor(C<sub>60</sub>-<i>I</i><sub>h</sub>)[5,6]fullerene C<sub>59</sub>(O)<sub>3</sub> Derivatives
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
Norfullerenes are fullerene-like compounds (fulleroids) resulting from partial deletion of fullerene skeleton carbons. The one carbon less norfullerene C59(O)3 derivatives having three carbonyl groups on the rim of the orifice are prepared through peroxide-mediated reactions. A key step involves a novel PCl5 initiated rearrangement of a hydroxyl amine adduct. Decarboxylation serves as the carbon removal step.
创建时间：
2016-02-27
