Bowl-to-Bowl Inversion Accelerated by the Introduction of Bulky 1,1,4,4-Tetramethylbutane-1,4-diyl Groups on Sumanene
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http://www.thieme-connect.com/DOI/DOI?10.1055/s-0035-1561473
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资源简介：
A variable-temperature 1H NMR study revealed that the bowl-to-bowl inversion of sumanene is accelerated by the introduction of bulky 1,1,4,4-tetramethylbutane-1,4-diyl groups on the peripheral aromatic ring. This is likely to be induced by a bowl flattening, as shown in the DFT-optimized structures.
提供机构：
© Georg Thieme Verlag
创建时间：
2016-06-22
